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12367 Electro-optic polymers for high speed modulators
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Balakrishnan, M. and Diemeer, M.B.J. and Driessen, A. and Faccini, M. and Verboom, W. and Reinhoudt, D.N. and Leinse, A. (2005) Electro-optic polymers for high speed modulators. In: Proceedings of the Annual Symposium of the IEEE/LEOS Benelux Chapter 2005, 1-2 December 2008, Mons, Belgium. pp. 313-316. Faculté Polytechnique de Mons, Service d'Electromagnétisme et Télécommunications. ISBN 2-9600226-4-5

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Abstract

Different electro-optic polymer systems are analyzed with respect to their electro-optic activity, glass transition temperature $(T_g)$ and photodefinable properties. The polymers tested are polysulfone (PS) and polycarbonate (PC). The electro-optic chromophore, tricyanovinylidenediphenylaminobenzene (TCVDPA), which was reported to have a highest photochemical stability [l] has been employed in the current work. Modified TCVDPA with bulky side groups has been synthesized, and a doubling of the electro-optic coefficient $(r_{33})$ compared to the unmodified TCVDPA has been shown. The plasticizing effect of the chromophore, has been reduced by attaching it to the polymer backbone. SU8 (passive) and PC-TCVDPA (active) channel waveguides were fabricated by photodefinition technique and the passive waveguide losses were measured to be 5 dB/cm at 1550nm.

Item Type:Conference or Workshop Paper (Full Paper, Poster)
Research Group:EWI-IOMS: Integrated Optical MicroSystems, TNW-MNF: Molecular Nanofabrication
Research Program:MESA-General
Research Project:Broadband and wavelength selective modulators for optical communications based on electro-optic polymers
ID Code:12367
Status:Published
Deposited On:04 June 2008
Refereed:Yes
International:No
More Information:statistics

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